Ziman Principles Of The Theory Of Solids 13 «PRO - 2024»

The perturbation $\delta V$ is the electron-phonon interaction Hamiltonian, $H_e-ph$. For long-wavelength acoustic phonons (sound waves), the lattice is locally dilated or compressed. A change in volume changes the bottom of the conduction band (or top of the valence band). This is captured by the deformation potential constant , $E_1$:

$$H_e-ph = \sum_\mathbfk, \mathbfk', \lambda M_\lambda(\mathbfq) , c_\mathbfk'^\dagger c_\mathbfk (a_\mathbfq\lambda + a_-\mathbfq\lambda^\dagger)$$ ziman principles of the theory of solids 13

The interaction Hamiltonian $H_e-ph$ does not just scatter electrons; it can create an effective attraction between two electrons. How? One electron emits a virtual phonon; a second electron absorbs it. This process is second-order in perturbation theory. This is captured by the deformation potential constant

If an ion at position $\mathbfR$ displaces by $\mathbfu(\mathbfR, t)$ due to a phonon, the potential $V(\mathbfr)$ experienced by an electron at position $\mathbfr$ changes. The total potential is: This process is second-order in perturbation theory

Introduction: The Bridge Between Lattice and Electron In the pantheon of solid-state physics literature, few texts carry the weight of Principles of the Theory of Solids by J. M. Ziman (or the closely related Solid State Theory by Walter A. Harrison). Chapter 13 stands as a pivotal summit in these works. By this stage, the reader has mastered the independent electron model (Chapter 6) and the physics of lattice vibrations, or phonons (Chapter 12). Chapter 13 is where these two worlds collide.

The net effective interaction is attractive for electrons near the Fermi surface with opposite momenta and spins ($\mathbfk, \uparrow$ and $-\mathbfk, \downarrow$) if: